In my youth, I painted several engines and have never used primer. I used engine paint in a spray can. Generally painted the block, valve covers, timing cover, water pump, and intake manifold. I like to cover or remove the alternator, p/s pump, and a/c compressor and their associated brackets. I think they look better without pain on them. Exhaust manifolds do not hold paint, even heat paint doesn't last long and they will stink as they burn the paint off. The rest of the engine generally needs a touch up every year or so. I also painted the engine compartments flat black. You can usually move the wiring harnesses and hoses out of the way without removing anything (there were a lot fewer of them thirty years ago).